Barton–Kellogg reaction
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The Barton–Kellogg reaction is a coupling reaction between a diazo compound and a thioketone, giving an alkene by way of an episulfide intermediate. The Barton–Kellogg reaction is also known as Barton–Kellogg olefination and Barton olefin synthesis.
Quick Facts Identifiers ...
Barton–Kellogg reaction | |
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Named after | Sir Derek Barton Richard M. Kellogg |
Reaction type | Coupling reaction |
Identifiers | |
RSC ontology ID | RXNO:0000495 |
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This reaction was pioneered by Hermann Staudinger, and also goes by the name Staudinger type diazo-thioketone coupling.